Product ID:47399 EPA PHASE V VOL ORG CMPD MIX 9
MSDS Date:04/07/1994
FSC:6850
NIIN:00F037694
MSDS Number: BWJRK

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

1,2,4,-TRICHLOROBENZENE

CAS: 120-82-1

RTECS: DC2100000

Fraction By Weight: 0.2%

OSHA PEL 5 PPM

ACGIH TLV: C 37 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,1,2-TRICHLOROETHANE (SUSPECTED ANIMAL CARCINOGEN BY IARC

CAS: 79-00-5

RTECS: KJ3150000

Fraction By Weight: 0.2%

OSHA PEL 45 MG/CUM

ACGIH TLV: 55 MG/CUM (SKIN)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *94-4*

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.2%

OSHA PEL 500 PPM

ACGIH TLV: 174 MG/CUM (A2)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG METHANOL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY CAUSE
RESPIRATORY FAILURE/LOW BLOOD PRESSURE (HYPOTENSION)/CNS
DEPRESSION/LIVER & KIDNEY DAMAGE. INGESTION: MAY BE FATAL. SKIN:
DERMATITIS. EYES: MAY CAUSE CORNEAL INJURY/BLIN DNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:BREATHING DIFFICULTY, HEADACHE, NAUSEA,
DIZZINESS, GI DISTURBANCES, NARCOSIS.

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER. INHALATION: IMMEDIATELY MOVE TO FRESH AIR. GIVE OXYGN/CPR IF
NECESSARY. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS.
NEVER TR Y TO MAKE AN UNCONSCIOUS PERSON VOMIT. GIVE 2 TABLESPOONS
OF BAKING SODA IN A GLASS OF WATER, PRESS FINGERS TO BACK OF TONGUE
TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:50F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT & BREATHING OF VAPORS.

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health

Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER =1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM & MAGNESIUM, METALS.
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:CO, CO2, FORMALDEHYDE, HYDROGEN
CHLORIDE, PHOSGENE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.